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Cyanide-free preparation of gold nanowires: controlled crystallinity, crystallographic orientation and enhanced field emission

The environmentally friendly preparation of nanomaterials with controlled structural features represents a development trend of nanoscience and nanotechnology. In this work, using a cyanide-free bath, gold nanowires with controlled crystallinity and preferred crystallographic orientation have been p...

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Published in:RSC advances 2015-01, Vol.5 (41), p.3213-3219
Main Authors: Lyu, Shuangbao, Lei, Dang Yuan, Liu, Wenqiang, Yao, Huijun, Mo, Dan, Chen, Yonghui, Hu, Peipei, Sun, Youmei, Liu, Jie, Duan, Jing Lai
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cited_by cdi_FETCH-LOGICAL-c312t-cc73388d06c48b456a5721824ab76d10bc04a36eaca1bbc5f97b5bc3466b11eb3
cites cdi_FETCH-LOGICAL-c312t-cc73388d06c48b456a5721824ab76d10bc04a36eaca1bbc5f97b5bc3466b11eb3
container_end_page 3219
container_issue 41
container_start_page 3213
container_title RSC advances
container_volume 5
creator Lyu, Shuangbao
Lei, Dang Yuan
Liu, Wenqiang
Yao, Huijun
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Liu, Jie
Duan, Jing Lai
description The environmentally friendly preparation of nanomaterials with controlled structural features represents a development trend of nanoscience and nanotechnology. In this work, using a cyanide-free bath, gold nanowires with controlled crystallinity and preferred crystallographic orientation have been prepared by electrochemical deposition in home-made polycarbonate ion track-etched templates. Single-crystal and polycrystal gold nanowires with preferred orientations along the [111] and [100] directions have been obtained by selecting fabrication parameters. The influence mechanisms of nanopore diameter, applied voltage, and deposition temperature on structural properties are proposed. In addition, single-crystal nanowires with [100] preferred orientation show enhanced field emission, which may be attributed to their single-crystal structure and the lower work function of loosely packed crystal planes. Gold nanowires with controlled crystallinity and preferred crystallographic orientations have been fabricated in ion track-etched templates using a cyanide-free bath.
doi_str_mv 10.1039/c5ra00994d
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source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects Crystallography
Deposition
Field emission
Gold
Nanostructure
Nanowires
Preferred orientation
Single crystals
title Cyanide-free preparation of gold nanowires: controlled crystallinity, crystallographic orientation and enhanced field emission
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