A Series of Lanthanide Frameworks with a Flexible Ligand, N,N′-Diacetic Acid Imidazolium, in Different Coordination Modes

{[La(trans-DAM)(cis-DAM)(H2O)2](ClO4)·3H2O} n (1), {[La2(trans-DAM)3(H2O)6](OH)3·7H2O} n (2), {[La(trans-DAM)2(H2O)2]Cl·4H2O} n (3), {[Nd(trans-DAM)2(H2O)2]X·3H2O} n (X = ClO4 (4), NO3 (5)), {[Nd(trans-DAM)(cis-DAM)(H2O)2]Cl·5H2O} n (6), and {[Nd(trans-DAM)2(H2O)2]Cl·5H2O} n (7) incorporating a flex...

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Published in:Crystal growth & design 2010-02, Vol.10 (2), p.658-668
Main Authors: Chai, Xiao-Chuan, Sun, Yan-Qiong, Lei, Ran, Chen, Yi-Ping, Zhang, Shuai, Cao, Yan-Ning, Zhang, Han-Hui
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Language:English
Subjects:
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Organic compounds
Other materials
Physics
Specific materials
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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cited_by cdi_FETCH-LOGICAL-a289t-4caf4d8a6459148828ed51419c36e3575179c9bc703f20942ac91f7352948a0a3
cites cdi_FETCH-LOGICAL-a289t-4caf4d8a6459148828ed51419c36e3575179c9bc703f20942ac91f7352948a0a3
container_end_page 668
container_issue 2
container_start_page 658
container_title Crystal growth & design
container_volume 10
creator Chai, Xiao-Chuan
Sun, Yan-Qiong
Lei, Ran
Chen, Yi-Ping
Zhang, Shuai
Cao, Yan-Ning
Zhang, Han-Hui
description {[La(trans-DAM)(cis-DAM)(H2O)2](ClO4)·3H2O} n (1), {[La2(trans-DAM)3(H2O)6](OH)3·7H2O} n (2), {[La(trans-DAM)2(H2O)2]Cl·4H2O} n (3), {[Nd(trans-DAM)2(H2O)2]X·3H2O} n (X = ClO4 (4), NO3 (5)), {[Nd(trans-DAM)(cis-DAM)(H2O)2]Cl·5H2O} n (6), and {[Nd(trans-DAM)2(H2O)2]Cl·5H2O} n (7) incorporating a flexible ligand HDAM (N,N′-diacetic acid imidazolium) were prepared in H2O or H2O/DMF (N,N′-dimethylformamide) solvents. Compounds 1 and 2 both contain the same 2D corrugated layers bridged by DAM− with different bridging modes to form different 3D structures, exhibiting tcs and (4,6)-connected topologies, respectively. The structural differences of 1 and 2 lie in the linkages of DAM− between the layers. Compound 3 also possesses a 3D architecture with an ant net, which is pillared by 2D (4,4) fan-shaped layers in an −ABAB− sequence. Compounds 4−6 contain similar 2D layers to 1 and 2. The analogous cationic structures 4 and 5 show a 4-connected sql net and 6 presents a (4,5)-connected network, resulting from the different modes of flag-like DAM− above and below the layers. Compound 7 with identical molecular formula to 6 displays a 2D double-layer, consisting of a couple of (4,4) rectangular grid layers. It exhibits a (3,6)-connected network. Additionally, IR and UV−visible spectroscopy, the luminescent properties, and thermogravimetric analyses are discussed.
doi_str_mv 10.1021/cg901075r
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Growth Des</addtitle><description>{[La(trans-DAM)(cis-DAM)(H2O)2](ClO4)·3H2O} n (1), {[La2(trans-DAM)3(H2O)6](OH)3·7H2O} n (2), {[La(trans-DAM)2(H2O)2]Cl·4H2O} n (3), {[Nd(trans-DAM)2(H2O)2]X·3H2O} n (X = ClO4 (4), NO3 (5)), {[Nd(trans-DAM)(cis-DAM)(H2O)2]Cl·5H2O} n (6), and {[Nd(trans-DAM)2(H2O)2]Cl·5H2O} n (7) incorporating a flexible ligand HDAM (N,N′-diacetic acid imidazolium) were prepared in H2O or H2O/DMF (N,N′-dimethylformamide) solvents. Compounds 1 and 2 both contain the same 2D corrugated layers bridged by DAM− with different bridging modes to form different 3D structures, exhibiting tcs and (4,6)-connected topologies, respectively. The structural differences of 1 and 2 lie in the linkages of DAM− between the layers. Compound 3 also possesses a 3D architecture with an ant net, which is pillared by 2D (4,4) fan-shaped layers in an −ABAB− sequence. Compounds 4−6 contain similar 2D layers to 1 and 2. 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Growth Des</addtitle><date>2010-02-03</date><risdate>2010</risdate><volume>10</volume><issue>2</issue><spage>658</spage><epage>668</epage><pages>658-668</pages><issn>1528-7483</issn><eissn>1528-7505</eissn><abstract>{[La(trans-DAM)(cis-DAM)(H2O)2](ClO4)·3H2O} n (1), {[La2(trans-DAM)3(H2O)6](OH)3·7H2O} n (2), {[La(trans-DAM)2(H2O)2]Cl·4H2O} n (3), {[Nd(trans-DAM)2(H2O)2]X·3H2O} n (X = ClO4 (4), NO3 (5)), {[Nd(trans-DAM)(cis-DAM)(H2O)2]Cl·5H2O} n (6), and {[Nd(trans-DAM)2(H2O)2]Cl·5H2O} n (7) incorporating a flexible ligand HDAM (N,N′-diacetic acid imidazolium) were prepared in H2O or H2O/DMF (N,N′-dimethylformamide) solvents. Compounds 1 and 2 both contain the same 2D corrugated layers bridged by DAM− with different bridging modes to form different 3D structures, exhibiting tcs and (4,6)-connected topologies, respectively. The structural differences of 1 and 2 lie in the linkages of DAM− between the layers. Compound 3 also possesses a 3D architecture with an ant net, which is pillared by 2D (4,4) fan-shaped layers in an −ABAB− sequence. Compounds 4−6 contain similar 2D layers to 1 and 2. The analogous cationic structures 4 and 5 show a 4-connected sql net and 6 presents a (4,5)-connected network, resulting from the different modes of flag-like DAM− above and below the layers. Compound 7 with identical molecular formula to 6 displays a 2D double-layer, consisting of a couple of (4,4) rectangular grid layers. It exhibits a (3,6)-connected network. Additionally, IR and UV−visible spectroscopy, the luminescent properties, and thermogravimetric analyses are discussed.</abstract><cop>Washington,DC</cop><pub>American Chemical Society</pub><doi>10.1021/cg901075r</doi><tpages>11</tpages></addata></record>
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subjects Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Organic compounds
Other materials
Physics
Specific materials
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
title A Series of Lanthanide Frameworks with a Flexible Ligand, N,N′-Diacetic Acid Imidazolium, in Different Coordination Modes
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