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Thermal and Thermomechanical Behaviour of Polycaprolactone and Starch/Polycaprolactone Blends for Biomedical Applications
Polycaprolactone (PCL) and starch/PCL blends (SPCL) are shown to have the potential to be used in a range of biomedical applications and can be processed with conventional melting‐based procedures. In this paper, the thermal and thermomechanical analyses of PCL and SPCL were performed, using DSC, op...
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Published in: | Macromolecular materials and engineering 2005-08, Vol.290 (8), p.792-801 |
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container_title | Macromolecular materials and engineering |
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creator | Wang, Yaming Rodriguez-Perez, Miguel A. Reis, Rui L. Mano, João F. |
description | Polycaprolactone (PCL) and starch/PCL blends (SPCL) are shown to have the potential to be used in a range of biomedical applications and can be processed with conventional melting‐based procedures. In this paper, the thermal and thermomechanical analyses of PCL and SPCL were performed, using DSC, optical microscopy and DMA. Starch effectively increased the non‐isothermal crystallisation rate of PCL. Non‐isothermal crystallisation kinetics was analyzed using Ozawa model, and a method, which combines the theories of Avrami and Ozawa. Starch effectively reinforced PCL and enhanced its damping properties, which indicated that SPCL could be more suitable than PCL in some biomedical applications, as it might help in the dissipation of the mechanical energy generated by the patient movements.
Dynamic mechanical behaviour of PCL and SPCL at 1 Hz. |
doi_str_mv | 10.1002/mame.200500003 |
format | article |
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Dynamic mechanical behaviour of PCL and SPCL at 1 Hz.</description><identifier>ISSN: 1438-7492</identifier><identifier>EISSN: 1439-2054</identifier><identifier>DOI: 10.1002/mame.200500003</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Applied sciences ; blends ; crystallization ; Exact sciences and technology ; Natural polymers ; Physicochemistry of polymers ; polycaprolactone ; starch ; Starch and polysaccharides ; thermal behavior ; thermomechanical behavior</subject><ispartof>Macromolecular materials and engineering, 2005-08, Vol.290 (8), p.792-801</ispartof><rights>Copyright © 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3973-c56f31600456ef17d35dc18c364b844d3dc0a349725d30ff72bfe10b30cf56493</citedby><cites>FETCH-LOGICAL-c3973-c56f31600456ef17d35dc18c364b844d3dc0a349725d30ff72bfe10b30cf56493</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmame.200500003$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmame.200500003$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,786,790,27957,27958,50923,51032</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17039384$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Yaming</creatorcontrib><creatorcontrib>Rodriguez-Perez, Miguel A.</creatorcontrib><creatorcontrib>Reis, Rui L.</creatorcontrib><creatorcontrib>Mano, João F.</creatorcontrib><title>Thermal and Thermomechanical Behaviour of Polycaprolactone and Starch/Polycaprolactone Blends for Biomedical Applications</title><title>Macromolecular materials and engineering</title><addtitle>Macromol. Mater. Eng</addtitle><description>Polycaprolactone (PCL) and starch/PCL blends (SPCL) are shown to have the potential to be used in a range of biomedical applications and can be processed with conventional melting‐based procedures. In this paper, the thermal and thermomechanical analyses of PCL and SPCL were performed, using DSC, optical microscopy and DMA. Starch effectively increased the non‐isothermal crystallisation rate of PCL. Non‐isothermal crystallisation kinetics was analyzed using Ozawa model, and a method, which combines the theories of Avrami and Ozawa. Starch effectively reinforced PCL and enhanced its damping properties, which indicated that SPCL could be more suitable than PCL in some biomedical applications, as it might help in the dissipation of the mechanical energy generated by the patient movements.
Dynamic mechanical behaviour of PCL and SPCL at 1 Hz.</description><subject>Applied sciences</subject><subject>blends</subject><subject>crystallization</subject><subject>Exact sciences and technology</subject><subject>Natural polymers</subject><subject>Physicochemistry of polymers</subject><subject>polycaprolactone</subject><subject>starch</subject><subject>Starch and polysaccharides</subject><subject>thermal behavior</subject><subject>thermomechanical behavior</subject><issn>1438-7492</issn><issn>1439-2054</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNqFkL1PwzAQxSMEEqWwMmdhTHvOOXEytlUpiLYgUcRouY6tBJI4sstH_nvSFhUkBrz46fx-76zneZcEBgQgHFaiUoMQIILu4JHXIxTTIISIHu90EjCahqfemXMvAIQlKfa8dpUrW4nSF3Xm77SplMxFXchuOFa5eC_Mm_WN9h9M2UrRWFMKuTG12iGPG2FlPvzzNi5VnTlfG-uPiy4y2-WNmqbsxKYwtTv3TrQonbr4vvve0_V0NbkJ5vez28loHkhMGQYyijWSGIBGsdKEZRhlkiQSY7pOKM0wkyCQpiyMMgStWbjWisAaQeoopin2vcE-V1rjnFWaN7aohG05Ab4tjm-L44fiOuBqDzTCdZ_WVtSycD8UA0wxoZ0v3fs-ilK1_6TyxWgx_b0j2LOF26jPAyvsK48Zsog_L2c8vlvNJxhSvsQvocCQLg</recordid><startdate>20050812</startdate><enddate>20050812</enddate><creator>Wang, Yaming</creator><creator>Rodriguez-Perez, Miguel A.</creator><creator>Reis, Rui L.</creator><creator>Mano, João F.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley-VCH</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20050812</creationdate><title>Thermal and Thermomechanical Behaviour of Polycaprolactone and Starch/Polycaprolactone Blends for Biomedical Applications</title><author>Wang, Yaming ; Rodriguez-Perez, Miguel A. ; Reis, Rui L. ; Mano, João F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3973-c56f31600456ef17d35dc18c364b844d3dc0a349725d30ff72bfe10b30cf56493</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Applied sciences</topic><topic>blends</topic><topic>crystallization</topic><topic>Exact sciences and technology</topic><topic>Natural polymers</topic><topic>Physicochemistry of polymers</topic><topic>polycaprolactone</topic><topic>starch</topic><topic>Starch and polysaccharides</topic><topic>thermal behavior</topic><topic>thermomechanical behavior</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Yaming</creatorcontrib><creatorcontrib>Rodriguez-Perez, Miguel A.</creatorcontrib><creatorcontrib>Reis, Rui L.</creatorcontrib><creatorcontrib>Mano, João F.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecular materials and engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Yaming</au><au>Rodriguez-Perez, Miguel A.</au><au>Reis, Rui L.</au><au>Mano, João F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal and Thermomechanical Behaviour of Polycaprolactone and Starch/Polycaprolactone Blends for Biomedical Applications</atitle><jtitle>Macromolecular materials and engineering</jtitle><addtitle>Macromol. Mater. Eng</addtitle><date>2005-08-12</date><risdate>2005</risdate><volume>290</volume><issue>8</issue><spage>792</spage><epage>801</epage><pages>792-801</pages><issn>1438-7492</issn><eissn>1439-2054</eissn><notes>ArticleID:MAME200500003</notes><notes>istex:9240ACC7C29BB80FA523EE184A755593A43C4DC3</notes><notes>ark:/67375/WNG-6KTLC324-N</notes><abstract>Polycaprolactone (PCL) and starch/PCL blends (SPCL) are shown to have the potential to be used in a range of biomedical applications and can be processed with conventional melting‐based procedures. In this paper, the thermal and thermomechanical analyses of PCL and SPCL were performed, using DSC, optical microscopy and DMA. Starch effectively increased the non‐isothermal crystallisation rate of PCL. Non‐isothermal crystallisation kinetics was analyzed using Ozawa model, and a method, which combines the theories of Avrami and Ozawa. Starch effectively reinforced PCL and enhanced its damping properties, which indicated that SPCL could be more suitable than PCL in some biomedical applications, as it might help in the dissipation of the mechanical energy generated by the patient movements.
Dynamic mechanical behaviour of PCL and SPCL at 1 Hz.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/mame.200500003</doi><tpages>10</tpages><oa>free_for_read</oa></addata></record> |
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identifier | ISSN: 1438-7492 |
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language | eng |
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source | Wiley-Blackwell Journals |
subjects | Applied sciences blends crystallization Exact sciences and technology Natural polymers Physicochemistry of polymers polycaprolactone starch Starch and polysaccharides thermal behavior thermomechanical behavior |
title | Thermal and Thermomechanical Behaviour of Polycaprolactone and Starch/Polycaprolactone Blends for Biomedical Applications |
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